The origin of high hydrogen content in kimberlitic olivine: Evidence from hydroxyl zonation in olivine from kimberlites and mantle xenoliths

Olivine macrocrysts in kimberlites are the most H-rich natural olivines known. Their xenocrystic provenance makes unclear whether H-enrichment occurred in the mantle prior to entrainment in kimberlite magma or during ascent. We present a Fourier transform infrared (FTIR) spectroscopy-based study of H zonation in kimberlite-derived olivine macrocrysts and/or olivine in xenoliths from the kimberlites Jericho (Nunavut, Canada), Beartooth (Northwest Territories, Canada), and Pipe 200 and Matsoku (Lesotho). The objective of the study was to determine whether changes in the concentration or speciation of H defects in proximity to the host kimberlite could yield insights into the origin of H-enrichment. Within the Group 1 region of the FTIR spectrum (similar to 3420-3700 cm(-1)), we find that olivines within xenoliths and macrocrysts show weak zonation or significant H depletions in rims. Peaks in the Group 2 region (similar to 3260-3420 cm(-1)) in Beartooth olivines show marked decrease in the crystal margins in comparison to Group 1 peaks. We find no preserved evidence for kimberlite-related H-enrichment in our dataset. We ascribe H depletion to diffusive H loss to infiltrating kimberlitic media. Diffusion models using coefficients previously applied to dehydrogenation of olivine and assuming a dry environment produce extremely short ascent durations incompatible with the results of other geospeedometers. This mismatch suggests that the poorly developed zonation in Jericho and Beartooth olivines indicates water-enrichment and/or faster ascent of these melts (in comparison to Pipe 200 and Matsoku), resulting in greater retention of mantle-derived H. A further significant factor in the mismatch is the differing speciation of H in most natural mantle-derived olivines in comparison to those used in diffusion experiments. We argue that the presence of presumably mantle-derived Group 2 H in olivine macrocrysts indicates rapid ascent of magma exsolving water-rich fluid, permitting preservation of these faster-diffusing defects only in particularly rapidly ascending kimberlite magmas. This interpretation explains empirical correlations between the presence of Group 2 bands, water-derived diamond resorption features, and volcaniclastic kimberlite facies. (C) 2014 Elsevier B.V. All rights reserved.