Title | Molybdenum and zinc stable isotope variation in mining waste rock drainage and waste rock at the Antamina mine, {Peru |
Publication Type | Journal Article |
Year of Publication | 2016 |
Authors | Skierszkan E.K, Mayer K.U, Weis D., Beckie R.D |
Journal | Science of The Total Environment |
Volume | 550 |
Pagination | 103–113 |
ISSN | 0048-9697 |
Keywords | Heavy stable isotopes, Mine drainage, Molybdenum, Multicollector ICP-MS, Zinc |
Abstract | {The stable isotope composition of molybdenum (Mo) and zinc (Zn) in mine wastes at the Antamina Copper–Zn–Mo mine, Peru, was characterized to investigate whether isotopic variation of these elements indicated metal attenuation processes in mine drainage. Waste rock and ore minerals were analyzed to identify the isotopic composition of Mo and Zn sources, namely molybdenites (MoS2) and sphalerites (ZnS). Molybdenum and Zn stable isotope ratios are reported relative to the NIST-SRM-3134 and PCIGR-1 Zn standards, respectively. δ98Mo among molybdenites ranged from − 0.6 to + 0.6‰ (n = 9) while sphalerites showed no δ66Zn variations (0.11 ± 0.01‰, 2 SD |
URL | http://www.sciencedirect.com/science/article/pii/S0048969716300535 |
DOI | 10.1016/j.scitotenv.2016.01.053 |