Molybdenum and zinc stable isotope variation in mining waste rock drainage and waste rock at the Antamina mine, {Peru

TitleMolybdenum and zinc stable isotope variation in mining waste rock drainage and waste rock at the Antamina mine, {Peru
Publication TypeJournal Article
Year of Publication2016
AuthorsSkierszkan E.K, Mayer K.U, Weis D., Beckie R.D
JournalScience of The Total Environment
Volume550
Pagination103–113
ISSN0048-9697
KeywordsHeavy stable isotopes, Mine drainage, Molybdenum, Multicollector ICP-MS, Zinc
Abstract

{The stable isotope composition of molybdenum (Mo) and zinc (Zn) in mine wastes at the Antamina Copper–Zn–Mo mine, Peru, was characterized to investigate whether isotopic variation of these elements indicated metal attenuation processes in mine drainage. Waste rock and ore minerals were analyzed to identify the isotopic composition of Mo and Zn sources, namely molybdenites (MoS2) and sphalerites (ZnS). Molybdenum and Zn stable isotope ratios are reported relative to the NIST-SRM-3134 and PCIGR-1 Zn standards, respectively. δ98Mo among molybdenites ranged from − 0.6 to + 0.6‰ (n = 9) while sphalerites showed no δ66Zn variations (0.11 ± 0.01‰, 2 SD

URLhttp://www.sciencedirect.com/science/article/pii/S0048969716300535
DOI10.1016/j.scitotenv.2016.01.053